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Anales de la Asociación Química Argentina
Print version ISSN 0365-0375
Abstract
PARAJON-COSTA, B. S.; WAGNER, C. C. and BARAN, E. J.. Vibrational spectra and electrochemical behavior of bispicolinate copper(II). An. Asoc. Quím. Argent. [online]. 2004, vol.92, n.1-3, pp.109-117. ISSN 0365-0375.
The infrared and Raman spectra of the Cu(II) complex of picolinic acid (Hpic), of stoichiometry [pic)2].2H2O were recorded and discussed by comparison with those of the free acid on the basis of Cu(its known structural data. The electrochemical properties of the complex were investigated in dimethylformamide solutions by cyclic voltammetry. The results show that its reduction occurs through a quasi-reversible one electron process, generating a Cu(I) species.
