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Revista de la Unión Matemática Argentina
versão Online ISSN 16699637
Rev. Unión Mat. Argent. v.49 n.2 Bahía Blanca jul./dez. 2008
The problem of entanglement of quantum states
G. A. Raggio
Abstract. We give a brief and incomplete survey of the problem of entanglement of states of composite quantum systems.
A quantum system is kinematically specified by a complex Hilbert space (there are hardly cases where a separable space will not do). The physical "observables" are identified with linear operators on . Usually the most interesting physical observables for continuous systems are given by unbounded operators; but one avoids this problem by exponentiation and works in the bounded linear operators on . Now is a algebra and a von Neumann algebra. In the 1960's  1980's there were serious attempts (all of them anticipated by J. von Neumann) to do away with the underlying Hilbert space and work directly with the abstract algebraic structure modeled by algebras or algebras (abstract von Neumann algebras)[1, 2, 3]. This was particularly fruitful when dealing with systems of infinitely many degrees of freedom (quantum fields, thermodynamic limits, etc.). The problem of entanglement which we want to address here can be formulated quite straightforwardly in this algebraic framework of quantum theory. But we will stick to the quantum mechanics of the 1930's and keep the Hilbert space. Mainly because the results which are available concern the finite dimensional case.
The "states" of the quantum system specified by are associated with the linear functionals which are positive (i.e., for all positive ), normalized (i.e., ) and normal (i.e., for any increasing family of selfadjoint operators which is uniformly bounded). It is this normality condition which guarantees that the states are in onetoone correspondence with positive trace class operators of unit trace (density operators) via the formula . This gives an extremely convenient representation of states and one often confuses the state as a linear functional with the associated density operator for which . States are automatically continuous, and satisfy . The complex number is interpreted probabilistically as the expected value of the "observable" associated with the operator when the system is in the state . The normalization condition is thus necessary for the consistency of this interpretation and the normality condition is seen as a noncommutative version of the additivity of probability measures.
Clearly states, which we will denote by , form a convex set which is closed with respect to the metric induced by the usual norm of linear functionals. Moreover, given any countable set and any countable set such that , the series converges in the norm of functionals to a state of .
In physical jargon (due to H. Weyl!) the extremal points of are called pure states. They are given by
here is the scalar product of . That is: the associated density operator is an orthogonal projection of rank one projecting onto some onedimensional subspace of . This orthoprojection is written ; and .
The representation theorem mentioned, and the spectral theorem for compact operators shows that the states are the closed convex hull of the pure states; in fact each state can be written as an infinite convex sum of extreme states:
But the convex decomposition into extremal elements is never unique. is never a (Choquet) simplex; quite the opposite is true: there are uncountably many convex decompositions and you can choose almost freely the "ingredients" which enter a decomposition. This is a key feature of quantum theory in contradistinction with classical theories whose state spaces are simplices.
Composition, separability and entanglement
If system is described by the Hilbert space and system by then the composite system "" is described by , the tensor product of the subsystem Hilbert spaces. This is the composition rule of quantum theory, and it is responsible for the most counterintuitive features of the theory. There are no indications from the real world that this rule is in need of change. I will consider mostly composition of two systems, but the definitions can be readily extended to more than two susbsytems. It is important to stress that we are always thinking of distinguishable (sub) systems and . The case of identical systems (bosons or fermions) is more involved and the entanglement issues are only partially understood.
One has although I will not explain what the on the right means, [8]. Given , define partial states , , by
Given and there is a unique element of written , such that
for all and all . A state of the composite system is product if ; that is, if and :
The product states, denoted by , not only do not show any correlation whatsoever between productobservables but also (for precisely that reason) the knowledge of the expected values of the observables of subsystem and of the expected values of the observables of subsystem allows one to construct the state of the composite system. Since convex sums of states can be interpreted classically as classical mixtures, the separable states or EPRcorrelation free states are defined as those in the closed convex hull of the productstates:
The states which are not separable are called entangled (verschränkt was the German word chosen by Schrödinger after his reaction [4, 5, 6] to the Einstein, Podolsky and Rosen paper [7]). In [4, 5], written in english, the words of Schrödinger are the following: ... I would not call that one but rather the characteristic trait of quantum mechanics, the one that enforces its entire departure from classical lines of thought. By interaction the two representatives [the quantum states] have become entangled.
A typical entangled state is a pure state associated to a onedimensional subspace such that the representative vector in this subspace is not a product vector: with and . Entangled states abound (mathematically) and naturally realized physical states are usually entangled (eigenstates of hamiltonians, thermal equilibrium states at low temperatures, etc.).
The problem is then: given a state of the composite system decide whether is separable or entangled. That is: are there states , states and weights such that ? The sum may be an infinite series, in which case it is automatically convergent with respect to the distance associated to the norm of continuous functionals. There is no loss of generality if one restricts to pure states and .
Via the representation theorem for states, one may rephrase the problem purely in terms of positive traceclass operators of unit trace on a Hilbert space tensor product; but the origin and flavor of the problem are then lost.
In the particular case where the given state is pure, the problem was solved many years ago by, essentially, Schrödinger [4, 5]. For a modern, direct and beautiful presentation of the problem in this particular case the reader is directed to section 118 of Jauch's book [9] (a book which can be recommended warmly to any mathematician interested in learning quantum mechanics). The solution is: pure is separable if and only if (or alternatively, ) is pure. Thus, one has to determine one of the partial states and then check for purity which is easily done in various alternative ways. The simplest is perhaps: take the trace of the square of the associated density operator; if this number is below the state is not pure, otherwise it is pure. This extends readily to the tensor product of any number of Hilbert spaces.
However, when the given state is not pure our knowledge is rather limited. For there is a criterion due to Wootters [10]; for and or , the positive partial transpose criterion of Peres and M. Horodecki, P. Horodecki and R. Horodecki, solves the problem. A recent review is [11]. Gurvits [12], has proved that when the Hilbert spaces involved are finite dimensional, the problem is NPhard in the hierarchy of computational complexity.
I describe the criteria just mentioned.
. Given let be the associated density operator, and put
where is the operator which for any orthonormal basis of has associated to it the matrix
with respect to the orthonormal basis of . denotes the complex conjugate of taking the product basis as real. Let be the eigenvalues of enumerated nondecreasingly according to their multiplicities.
Theorem 1. is separable if and only if (equivalently: ).
2.2. Positive Partial Transpose Criterion.
, . Choose orthonormal bases for and for . Identify the tensor product such that the matrix associated to in the product orthonormal basis of is
The general operator in has the form
Let
This is the partial transpose with respect to the first factor (one could proceed just as well with transposition with respect to the second factor).
Given , let be the associated density operator; then
Theorem 2. is separable if and only if .
For the tensor product of two Hilbert spaces the positivity condition on the partial transpose is always necessary for separability irrespective of dimensions, as observed by A. Peres. The proof of sufficiency given by M. Horodecki, P. Horodecki and R. Horodecki [13], makes heavy use of the classification of positive linear maps of the complex matrices due to E. Størmer and S.L. Woronowicz. For and there are counterexamples (P. Horodecki): but is entangled. This happens whenever the dimension of the tensor product Hilbert space exceeds .
 In 1964, some thirty years after the EPR paper, J.S. Bell [14] succeeded in capturing and quantifying the separability/entanglement issue in an inequality involving expectation values (correlation inequality).
for every pair of selfadjoint in the unit ball of and every pair of selfadjoint in the unit ball of The inequality in brackets is just the triangle inequality and valid for any state. Assume is a product state, i.e., ; then Since , and , we obtain
If now is a convex sum of product states, i.e., , then  using the triangle inequality, the positivity of and the relation ,
Finally, if is a limit of states which are convex sums of product states, in a topology which makes expectation values continuous, then the inequality persists.
For many years after 1964, "entanglement" was informally identified with "violation of Bell's inequality".
 The next huge leap forward was taken by R.F. Werner in 1989, [15]. For , , he succeeded in constructing a family of entangled states which satisfy the inequality of Theorem 3 (or any other such correlation inequality which is necessary for separability). He thus showed that Belltype correlation inequalities could not decide the issue. Werner does this by constructing a socalled "local hiddenvariable model" for his states. In the present case of operators with discrete spectrum (denoted by ), this means: Given a state de ,
 Find a measurable space
 For each find a function such that , a.e. for every and
 For each find a function such that , a.e. for every and

where is the spectral orthoprojector of associated to the eigenvalue and that of associated to the eigenvalue .
The qualifier "local" of the hiddenvariable model is expressed by the fact that and are independent. The correlation inequalities à la Bell are consequences of the integral formula: on the lefthand side we have the expectation of a product with respect to a probability measure.
 Consider the following simple separability/entanglement criterion used by R.F. Werner in his seminal paper just described. If , let be the continuous linear extension of (the flip):
Consider the pure product state associated to , , that is . Then, . Then, if , is a limit of convex sums of pure product states, and thus:
However, there are abundant entangled states with . gives a simple example of a socalled entanglement witness. It is an instance of the HahnBanach separation theorem for convex sets: given a closed convex set (e.g., the separable states) a point not in the set can be separated by a hyperplane.
Other, different, criteria have been established (more along the nongeometric lines of the positive partial transpose criterion; see 2.2.) which constitute necessary conditions for separability.
Among these, the range criterion [16] asserts that if the state is separable, then there are product vectors spanning the range of the density operator associated to and such that spans that of the partial transpose . This criterion is able to detect entanglement of states with positive partial transpose.Another class of necessary conditions for separability arises from certain maps which are contractive with respect to the tracenorm . Suppose the linear map mapping into itself, satisfies for all unit vectors and . Then if is separable and is the associated density operator, one has that . An example of such a map is the realignment or reshuffling map for the case , [17], defined by matrix elements with respect to a product basis by:
For twenty years now research on the problem has been going strong fueled mainly by the idea that entangled quantum states can be used as carriers of information, and that these bits combined to "quantum computers" can overcome some of the limitations of "classical computers". A very good review of the subject of "quantum vs. classical computation" is [18].
Although enormous progress has been made in understanding the subtleties of entanglement the basic problem of deciding whether or not a given state is or isn't entangled remains open.  When considering entanglement with respect to more than two subsystems, all the possible bipartite entanglement information for a given state is generically useless. A concrete example for with is given in [19]. For unitary vectors , with , let . Let be the orthoprojector onto the subspace spanned by the four pairwise orthogonal vectors: , , , . Now is a density operator acting on ; the associated state is not separable but it is, nevertheless, separable for each of the three possible bipartitions of the system:
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G. A. Raggio
FaMAF,
Universidad Nacional de Córdoba,
Córdoba 5000, Argentina
Recibido: 10 de noviembre de 2008
Aceptado: 26 de noviembre de 2008